First, is there a full command list for the hotkeys?

Second, if there is no such thing, I need help with a hotkey command.

I'm trying to make a hotkey that switches to a specific VWM.

Here's my humble try.

*Hotkey CTRL 1 !VWM1 ;change to desktop 1
*Hotkey CTRL 2 !VWM1 ;change to desktop 2

and so forth.

How should i do it, this apperently doesn't work so... HELP! :)

Hotkeys take actions, whether that be executables or, bangs--those words with a '!' in front of them.
Use valid bangs. They are in the modules' documentation.
Or see the bangs list in the dialog of !About if you know which one you want.